| QUATERNARY CHRONOLOGY AND DATING James S. Aber |
| Introduction | Radiometric dating |
| Radiocarbon dating | Fission-track dating |
| Cosmogenic dating | Paleomagnetism |
| Amino-acid dating | Lichenometry |
| Related sites | References |
The model of four Quaternary glaciations served well for more than half a century. Since the 1960s, however, much new evidence has accumulated that indicates: (1) the Quaternary began at least 1½ million years ago, perhaps more than 2 million years BP, and (2) many more than four glaciations took place during the Quaternary. The exact number of major glacial cycles is not known, but is at least ten or probably more, each lasting about 100,000 years in duration.
The beginning date of the Quaternary is the subject of continuing discussion among geologists. Officially the Tertiary-Quaternary (Pliocene-Pleistocene) boundary is set in a stratotype at Vrica, Italy, which is dated around 1.8 million years old. However, much controversy surrounds the selection of this stratotype to represent the Tertiary-Quaternary boundary. Many Quaternary scientists want to select another, older boundary at about 2.6 million years ago (Morrison and Kukla 1998); whereas others are adamant to retain the Vrica boundary at 1.8 million years old (Aubry et al. 1998). An increasing amount of evidence favors rapid buildup of glaciation in different parts of the world by 2½ million years ago (Prueher and Rea 1998). However, this debate will not be settled anytime soon.
Determining the age of Quaternary events is like timing the Olympic 100-meter sprint in comparison to the marathon of geologic time. It is feasible, but technically difficult. Millennia, centuries, and even decades are important time spans for Quaternary dating. New geophysical techniques for dating geologic materials have revolutionized Quaternary chronology. These techniques have been developed and refined during the past few decades. Among the most important are several means of radiometric dating based on carbon-14, argon-argon, chlorine-36, beryllium-10, and uranium-thorium (Hall 1995). Non-radiometric dating techniques employ paleomagnetism, amino acids, tree rings, weathering rinds, lichens, and other materials. In order to determine environmental and climatic relationships, it is critically important to accurately date Quaternary records (Nesje and Dahl 2000).
Half lives of different isotopes vary enormously from less than one second to
billions of years. The effective interval for geologic dating using any
particular isotope is from about 1/10th half life (minimum) to 10 half
lives (maximum). This interval is related to the analytical limits of
laboratory measurements of radioactive isotopes. After 10 half lives, less than
1/1000th of the parent isotope still remains--too little to detect (Hall
1995). Several geologically common isotopes have half lives of appropriate lengths
for dating Quaternary materials. For example, the argon-argon method has
proven quite effective for dating volcanic deposits of Pleistocene eruptions--see
Fig. 10-2.
Upon death, the amount of 14C in tissues of a plant or animal body begins to decline as 14C decays into nitrogen. This nitrogen normally escapes from the body and cannot be measured. The amount of remaining 14C can be measured, however, and this is the basis for the radiocarbon dating method. The method was first developed by the chemist W.F. Libby in 1950, for which he won a Nobel prize in 1960. The critical assumption for radiocarbon dating is that the dated material originally
contained 14C in the same abundance as the atmosphere.
Given its half life (std. value of 5570 years), a dating range of a few
centuries to around 50,000 years is possible. Older material simply has
too little remaining 14C to measure accurately. Several analytical
techniques are in use for radiometric dating: proportional gas counting,
liquid scintillation, and negative-ion accelerator mass spectrometry
(AMS)--see Fig. 10-4. During measurement of a sample's
radioactivity, decay activity normally varies slightly about a mean value.
Thus radiometric dates are given with a standard deviation, for example
10,000±500 years BP. This indicates the dated age lies between 9,500 and
10,500 years ago; BP means "before present" (1950).
Radiocarbon dating has proven enormously popular and useful for dating a host of geologic and archeologic materials. The best materials are considered to be organic: wood, peat, charcoal, leather, textiles, etc. Organic hard parts, such as bones, aquatic shells, bird eggshell, and teeth, are next in suitability for dating. Glacier ice, steel, and many other materials may also be dated using radiocarbon, as long as the critical assumption is met. Even mortar in ancient buildings can be dated by radiocarbon (Hale et al. 2003). On the basis of radiocarbon dating a detailed chronology is now established for Late Quaternary events.
As with any dating method, complications and limitations exist for
radiocarbon dating. The basic assumption is that atmospheric 14C has
remained constant through time. This is certainly not true for this
century. Massive burning of fossil fuel has released much 12C into the
atmosphere, whereas atmospheric nuclear explosions have created much 14C.
The atmospheric 14C constant used for radiocarbon dating is therefore
based on wood samples from the 1800s.
Radiocarbon dating may be compared directly to tree
rings dated by dendrochronology. Bristlecone pine (Pinus
aristata) has the longest tree-ring record, extending back more than
8000 years, covering nearly all of the Holocene. In general, radiocarbon
dates less than 3500 years BP turn out to be slightly too old, whereas
dates greater than 3500 years BP are several centuries too young. This
indicates that atmospheric 14C has varied in the past, presumably because
of changes in the sun's or earth's magnetic fields. A tree-ring
calibration now allows for correction of Holocene radiocarbon dates,
however older radiocarbon dates cannot be corrected. For this reason older
radiocarbon dates are not regarded as true year dates; such dates are
reported as radiocarbon years.
Other conditions complicate radiocarbon dating. Some organisms are able to
preferentially take up 12C and thus partially exclude 14C from their
bodies. Living plants normally contain 3-4% less 14C than the atmosphere,
which could yield age discrepancies for older samples. This photosynthesis
effect can be corrected by reference to 13C, a stable isotope. Certain
species of shellfish are able to exclude most 14C from construction of
their shells. These species yield anomalously old dates.
Plants, animals, and organic deposits in lakes may be subject to a
hard-water effect, in which carbon is derived not
only from the atmosphere but also from weathering of older rocks in the
lake basin. Erroneous dates that are too old result from such conditions.
This is a particular problem in the northern Great Plains region, where
glacial sediment contains much reworked limestone, dolostone, coal, and
lignite. Many radiocarbon dates obtained from aquatic materials--shells,
peat, and organic-rich soils--have proven to be 1000s of years too old.
Only dates of samples obtained from dryland sites are considered valid--see
Fig. 10-5.
Finally the problem of sample contamination by later events must always be
taken into account. Growth of modern plant roots or chemical changes
brought about by ground-water circulation may alter the 14C content of a
potential sample. In spite of the pitfalls for radiocarbon dating, it is
regarded as indispensable for Late Quaternary chronology and is widely used
for all manner of geological, biological, and archeological sample
materials. The AMS radiocarbon dating technique has become especially
important for providing accurate dates in critical situations (i.e.
Fleisher et al. 1999).
Fission-track dating is complicated in two ways: (1) determining the
uranium content of a sample and (2) fission-track annealing. Uranium
content is determined by comparing the spontaneous (natural,
238U) fission tracks to induced (artificial, 235U)
fission tracks--see Fig. 10-6. Inducing 235U fission tracks
is done by irradiating the sample with
high-energy neutrons in a nuclear reactor. The number of induced fission
tracks depends on the sample's uranium content and the neutron dose. The
two uranium isotopes always occur in the same ratio in nature; thus, the
number of induced fission tracks is a measure of total uranium content in a
sample.
Fission-track annealing takes place over time, as the minute damage tracks
recrystallize and disappear. The rate of annealing depends on temperature
and type of material. High temperature accelerates annealing; thus,
fission-track dating gives the age since the sample has cooled below
metamorphic temperatures. Glass is especially subject to annealing even at
low temperature. This effect is demonstrated by the Huckleberry Ridge ash
of the Yellowstone region (Naeser and Naeser 1988). Fission-track dates on
glass usually fall in the 1.2 to 1.4 million years BP range; whereas,
fission-track dates on zircon crystals are consistently 1.9 million years
BP. Other types of dating support the 1.9 million year age for the
Huckleberry Ridge ash.
The orientation of the Earth's magnetic field at any point is specified by
two measurements: declination (trend) and inclination
(plunge). The inclination varies from horizontal at the equator to
vertical at the poles--see Fig. 10-9. The field is directed
downward in the northern hemisphere and upward in the southern hemisphere
at present. The magnetic field periodically reverses its polarity at
intervals ranging from several 1000 to > 1 million years; during reversed
polarity, a compass needle would point south.
Polarity reversals should be excellent stratigraphic markers. Reversals
are global in extent, they are detectable in many kinds of rocks and
sediments, and the ages of reversals can be dated by radiometric
techniques. Remnant magnetism of samples is measured using either spinner
or astatic magnetometers. Secondary remnant magnetism acquired long after
the time of rock formation is a troublesome factor. The effects of
secondary magnetism can usually be removed from samples by stepwise
demagnetization. Various field tests may also be applied to determine the
origin of natural remnant magnetism in samples.
A detailed record of paleomagnetic reversals is available for the Cenozoic
Era--see Fig. 10-10. Positive (normal) intervals are numbered, while
reversed episodes are unnumbered; the younger anomalies have been given
individual names. The Neogene/Quaternary boundary is currently defined at
the end of anomaly 2 (Olduvai event = 1.6 million years BP); and the
Early/Middle Pleistocene boundary is set at the beginning of anomaly 1
(Brunhes epoch = 720,000 years BP). The Blake event was a short-lived
reversal during the Brunhes epoch, about 123,000 to 117,000 years BP
(Abrahamsen 1995). It corresponds to the Sangamon/Eemian high stand of sea
level.
By itself, paleomagnetism cannot give an absolute date. However, in
combination with other dating techniques it may further refine or verify
the age of Quaternary sediments, rocks, and fossils.
Most amino-acid dating work has been done using leucine or isoleucine in
marine mollusks (Wehmiller et al. 1988), and aspartic acid in
conifer wood has also proven useful (Rutter and Vlahos 1988). Sample
material is analyzed with various gas chromatographic methods. In the case
of marine mollusks, the D/L isoleucine ratio increases from nearly zero in
modern shells to equilibrium (maximum) values of about 1.30±0.05. The
time required to reach the equilibrium ratio depends on the effective
temperature experienced by the fossil. At +10ºC, it takes about 2 million
years; at -10ºC, 20 million years are required (Miller and Mangerud 1985).
D/L ratios cannot be directly compared for different amino acids or between
different species.
Amino-acid ratios can be used for either relative or absolute dating.
Absolute dating requires calibration with radiometric techniques, such as
radiocarbon dates, and knowledge of the temperature history of the
fossil--see Fig. 10-11. Once such information is established for a
region, amino-acid dating may be used with confidence. However,
amino-acid time calibration cannot be extended beyond the area of study due
to regional differences in temperature history. Amino-acid dating is
particularly useful for verifying the ages of fossils that were dated with
other techniques.
The aminostratigraphy of northwestern Europe has been studied in
considerable detail. A regional stratigraphy of marine benthic
foraminiferas is based on species with similar racemization rates. Times
of high sea level and marine deposition during interglaciations are
documented for late and middle Pleistocene--see Fig. 10-12. D/L
ratios fall into four groups.
Remember: send your comments and questions via e-mail to the instructor.
Radiometric dating
Radiometric dating depends on the well-documented assumption that each
radioactive isotope decays at a specific and constant rate. The decay rate
for an isotope is most easily illustrated by its half life--see
Fig. 10-1. The half life is the length of time necessary for
one-half of the original mass of the parent isotope to decay into daughter
isotopes.
Pinitial ===>
Px + DxRadiocarbon dating
Radiocarbon (14C) is undoubtedly the most important for dating latest
Pleistocene and Holocene sediments and fossils.Carbon occurs in three isotopic forms:
12C (99%), 13C (1%), and 14C (< 1). Only
14C is radioactive; its half life is about 5600 years. 14C is
produced in minute quantities in the upper atmosphere by cosmic radiation--see Fig.
10-3. Assuming constant production and constant decay of 14C, a balance
is achieved in 14C content of the atmosphere. Radiocarbon is readily circulated
as CO2 and is incorporated into the bodies of plants and animals as
well as in surface water and ice. While living, plants and animals contain in
their tissues a 14C to 12C ratio that is equal to that of
the atmosphere.
Paleomagnetism
Iron-bearing rocks and sediments may acquire at the time of their formation
a natural remnant magnetism. This primary magnetism is aligned
parallel to the existing magnetic field of the Earth. Remnant magnetism
may be acquired through thermal, chemical, or depositional means. Volcanic
lava, chemical sediment, and even till often preserve a stable primary remnant
magnetism. Such rocks and sediments can be used as "fossil compasses" to
determine the nature of the Earth's paleomagnetic field.Amino-acid dating
All living organisms contain proteins made up of amino
acids. The proteins produced by organisms consist almost entirely of
amino acids in the L-isomer (left-handed) configuration. Upon death, the L
amino acids begin inverting to their respective D-isomer (dextral or right-handed)
configurations. This process is called racemization. Each of the
20 common amino acids undergoes its own inversion from L to D forms at
rates that depend mainly on temperature and secondarily on taxonomy
(species). D/L ratios in fossil organic material are functions of time,
temperature and species.
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